Synthesis of 4-Trialkylsilyl(Germyl)-1H-1,2,3-Triazolecarbaldehyde Oximes

Methods for the synthesis of 4-trialkylsilyl(germyl)-1H-1,2,3-triazole-5-carbaldehyde oximes have been developed. Microwave activation was shown to be highly efficient in the oximation of 1H-1,2,3-triazole-5-carbaldehydes containing silicon or germanium and also in achieving a multicomponent synthes...

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Veröffentlicht in:	Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2014-10, Vol.50 (7), p.967-971
Hauptverfasser:	Medvedeva, A. S., Demina, M. M., Konkova, T. V., Vu, T. D., Larina, L. I.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical tests and reagents Chemistry Chemistry and Materials Science Hydroxides Organic Chemistry Pharmacy Triazoles
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Methods for the synthesis of 4-trialkylsilyl(germyl)-1H-1,2,3-triazole-5-carbaldehyde oximes have been developed. Microwave activation was shown to be highly efficient in the oximation of 1H-1,2,3-triazole-5-carbaldehydes containing silicon or germanium and also in achieving a multicomponent synthesis of 4-trialkylsilyl-1H-1,2,3-triazole-5-carbaldehyde oxime via the reaction of 3-trimethyl-silylprop-2-yn-1-al with trimethylsilyl azide and hydroxylamine.
ISSN:	0009-3122 1573-8353
DOI:	10.1007/s10593-014-1551-y