An Effective Activation of Palladium Phosphine Complexes in Aqueous Phase Reactions of Hetero-Aromatic Boronic Acids with Aryl Halides
We have developed a simple and effective method for the activation of palladium phosphine complexes in the Suzuki reaction (TON up to 9800, TOF up to 58800 h -1 ) by selecting an aqueous reaction medium instead of organic solvents. This method was elaborated for a high yield synthesis of heteroaroma...
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Veröffentlicht in: | Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2014-04, Vol.50 (1), p.19-25 |
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container_title | Chemistry of heterocyclic compounds (New York, N.Y. 1965) |
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creator | Bumagin, N. A. Veselov, I. S. Belov, D. S. |
description | We have developed a simple and effective method for the activation of palladium phosphine complexes in the Suzuki reaction (TON up to 9800, TOF up to 58800 h
-1
) by selecting an aqueous reaction medium instead of organic solvents. This method was elaborated for a high yield synthesis of heteroaromatic biaryls with furyl and thienyl groups. |
doi_str_mv | 10.1007/s10593-014-1443-1 |
format | Article |
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-1
) by selecting an aqueous reaction medium instead of organic solvents. This method was elaborated for a high yield synthesis of heteroaromatic biaryls with furyl and thienyl groups.</description><identifier>ISSN: 0009-3122</identifier><identifier>EISSN: 1573-8353</identifier><identifier>DOI: 10.1007/s10593-014-1443-1</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Chemical tests and reagents ; Chemistry ; Chemistry and Materials Science ; Halides ; Organic Chemistry ; Palladium ; Pharmacy ; Substitution reactions</subject><ispartof>Chemistry of heterocyclic compounds (New York, N.Y. 1965), 2014-04, Vol.50 (1), p.19-25</ispartof><rights>Springer Science+Business Media New York 2014</rights><rights>COPYRIGHT 2014 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c327t-51513538ba3117ef0a2c167a56596f57fa00f31d9d273dfc77f9d7f9eee5d4493</citedby><cites>FETCH-LOGICAL-c327t-51513538ba3117ef0a2c167a56596f57fa00f31d9d273dfc77f9d7f9eee5d4493</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10593-014-1443-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10593-014-1443-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Bumagin, N. A.</creatorcontrib><creatorcontrib>Veselov, I. S.</creatorcontrib><creatorcontrib>Belov, D. S.</creatorcontrib><title>An Effective Activation of Palladium Phosphine Complexes in Aqueous Phase Reactions of Hetero-Aromatic Boronic Acids with Aryl Halides</title><title>Chemistry of heterocyclic compounds (New York, N.Y. 1965)</title><addtitle>Chem Heterocycl Comp</addtitle><description>We have developed a simple and effective method for the activation of palladium phosphine complexes in the Suzuki reaction (TON up to 9800, TOF up to 58800 h
-1
) by selecting an aqueous reaction medium instead of organic solvents. This method was elaborated for a high yield synthesis of heteroaromatic biaryls with furyl and thienyl groups.</description><subject>Chemical tests and reagents</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Halides</subject><subject>Organic Chemistry</subject><subject>Palladium</subject><subject>Pharmacy</subject><subject>Substitution reactions</subject><issn>0009-3122</issn><issn>1573-8353</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNp9kN1qGzEQhUVoIK6bB8idXkCpZrWyvJdb49YBQ01Ir4UijWKFXcmV1m3zAn3uanGuyzAc5ucbmEPIHfB74Fx9LsBlJxiHlkHbCgZXZAFSCbYWUnwgC855xwQ0zQ35WMprLRWs2wX520e69R7tFH4h7WcxU0iRJk8PZhiMC-eRHo6pnI4hIt2k8TTgHyw0RNr_PGM6lzo2BekjGjujZWZ3OGFOrM9prPcs_ZJyilV7G1yhv8N0pH1-G-jODMFh-USuvRkK3r7rkvz4un3a7Nj--7eHTb9nVjRqYhIk1H_Wz0YAKPTcNBZWysiV7FZeKm849wJc5xolnLdK-c7VRETp2rYTS3J_uftiBtQh-jRlY2s4HINNEX2o_V6sZculUG0F4ALYnErJ6PUph9HkNw1cz87ri_O6Oq9n5zVUprkwpe7GF8z6NZ1zrH_9B_oHDJqHWQ</recordid><startdate>20140401</startdate><enddate>20140401</enddate><creator>Bumagin, N. A.</creator><creator>Veselov, I. S.</creator><creator>Belov, D. S.</creator><general>Springer US</general><general>Springer</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20140401</creationdate><title>An Effective Activation of Palladium Phosphine Complexes in Aqueous Phase Reactions of Hetero-Aromatic Boronic Acids with Aryl Halides</title><author>Bumagin, N. A. ; Veselov, I. S. ; Belov, D. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c327t-51513538ba3117ef0a2c167a56596f57fa00f31d9d273dfc77f9d7f9eee5d4493</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Chemical tests and reagents</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Halides</topic><topic>Organic Chemistry</topic><topic>Palladium</topic><topic>Pharmacy</topic><topic>Substitution reactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Bumagin, N. A.</creatorcontrib><creatorcontrib>Veselov, I. S.</creatorcontrib><creatorcontrib>Belov, D. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Chemistry of heterocyclic compounds (New York, N.Y. 1965)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Bumagin, N. A.</au><au>Veselov, I. S.</au><au>Belov, D. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An Effective Activation of Palladium Phosphine Complexes in Aqueous Phase Reactions of Hetero-Aromatic Boronic Acids with Aryl Halides</atitle><jtitle>Chemistry of heterocyclic compounds (New York, N.Y. 1965)</jtitle><stitle>Chem Heterocycl Comp</stitle><date>2014-04-01</date><risdate>2014</risdate><volume>50</volume><issue>1</issue><spage>19</spage><epage>25</epage><pages>19-25</pages><issn>0009-3122</issn><eissn>1573-8353</eissn><abstract>We have developed a simple and effective method for the activation of palladium phosphine complexes in the Suzuki reaction (TON up to 9800, TOF up to 58800 h
-1
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subjects | Chemical tests and reagents Chemistry Chemistry and Materials Science Halides Organic Chemistry Palladium Pharmacy Substitution reactions |
title | An Effective Activation of Palladium Phosphine Complexes in Aqueous Phase Reactions of Hetero-Aromatic Boronic Acids with Aryl Halides |
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