Synthesis of Macrocyclic Derivatives of the Diterpenoid Isosteviol with Two and Four ent-Beyerane Frameworks

Synthesis of Macrocyclic Derivatives of the Diterpenoid Isosteviol with Two and Four ent-Beyerane Frameworks

Macrocycles with two or four ent-beyerane diterpenoid frameworks joined by ester spacers with various polymethylene chain lengths (n = 2, 6, 8) were synthesized for the first time from the diterpenoid isosteviol (16-oxo-ent-beyeran-19-oic acid).

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Veröffentlicht in:Chemistry of natural compounds 2013-07, Vol.49 (3), p.462-466
Hauptverfasser: Strobykina, I. Yu, Babaev, V. M., Rizvanov, I. Kh, Kataev, V. E.
Format: Artikel
Sprache:eng
Schlagworte:
Medicine
Organic Chemistry
Pharmacy
Plant Sciences
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Zusammenfassung:Macrocycles with two or four ent-beyerane diterpenoid frameworks joined by ester spacers with various polymethylene chain lengths (n = 2, 6, 8) were synthesized for the first time from the diterpenoid isosteviol (16-oxo-ent-beyeran-19-oic acid).
ISSN:0009-3130
1573-8388
DOI:10.1007/s10600-013-0639-4