Frequency dependence of the electrical conductivity in Ag/PAN nanocomposites

Frequency dependence of the electrical conductivity in Ag/PAN nanocomposites

The frequency dispersion of the electrical conductivity of silver/polyacrylonitrile nanocomposite films is studied at various temperatures and AgNO 3 contents in an initial mixture. The frequency dependences of the nanocomposites in the range 10 3 –10 6 Hz are found to be well described by power law...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Technical physics 2012-07, Vol.57 (7), p.965-970
Hauptverfasser: Kudryashov, M. A., Mashin, A. I., Logunov, A. A., Chidichimo, G., De Filpo, G.
Format: Artikel
Sprache:eng
Schlagworte:
Classical and Continuum Physics
Electric properties
Electrical conductivity
Nanotechnology
Physics
Physics and Astronomy
Polymers
Solid State
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The frequency dispersion of the electrical conductivity of silver/polyacrylonitrile nanocomposite films is studied at various temperatures and AgNO 3 contents in an initial mixture. The frequency dependences of the nanocomposites in the range 10 3 –10 6 Hz are found to be well described by power law f 0.8 . A charge transfer mechanism responsible for the conductivity of the nanocomposites is proposed. Silver clusters Ag 4 2+ and Ag 8 2+ are assumed to be present in the polymer.
ISSN:1063-7842
1090-6525
DOI:10.1134/S1063784212070134