Structural and sorption characteristics of the products from zeolitization of sba-15 in the presence of tetraalkylammonium hydroxides

Micro–mesoporous materials combining the structural and sorption characteristics of a mesoporous molecular sieve (MMS) and zeolite BEA were obtained by the “dry gel conversion” method – partial zeolitization of silica MMS SBA-15 in the presence of tetraethylammonium hydroxide. The volume of the meso...

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Veröffentlicht in:Theoretical and experimental chemistry 2011-09, Vol.47 (4), p.257-263
Hauptverfasser: Lysenko, N. D., Il’in, V. G., Yaremov, P. S.
Format: Artikel
Sprache:eng
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Zusammenfassung:Micro–mesoporous materials combining the structural and sorption characteristics of a mesoporous molecular sieve (MMS) and zeolite BEA were obtained by the “dry gel conversion” method – partial zeolitization of silica MMS SBA-15 in the presence of tetraethylammonium hydroxide. The volume of the mesopores reaches 0.65 cm 3 /g, while that of the micropores is in the region of 0.1 cm 3 /g. The acidity of the obtained zeolitized materials differs from that of BEA; the total concentration of medium-strength acid centers (maximum thermal desorption of ammonia at ~315 °C) amounts to 0.15 mmol/g.
ISSN:0040-5760
1573-935X
DOI:10.1007/s11237-011-9213-y