Structural and sorption characteristics of the products from zeolitization of sba-15 in the presence of tetraalkylammonium hydroxides
Micro–mesoporous materials combining the structural and sorption characteristics of a mesoporous molecular sieve (MMS) and zeolite BEA were obtained by the “dry gel conversion” method – partial zeolitization of silica MMS SBA-15 in the presence of tetraethylammonium hydroxide. The volume of the meso...
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Veröffentlicht in: | Theoretical and experimental chemistry 2011-09, Vol.47 (4), p.257-263 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Micro–mesoporous materials combining the structural and sorption characteristics of a mesoporous molecular sieve (MMS) and zeolite BEA were obtained by the “dry gel conversion” method – partial zeolitization of silica MMS SBA-15 in the presence of tetraethylammonium hydroxide. The volume of the mesopores reaches 0.65 cm
3
/g, while that of the micropores is in the region of 0.1 cm
3
/g. The acidity of the obtained zeolitized materials differs from that of BEA; the total concentration of medium-strength acid centers (maximum thermal desorption of ammonia at ~315 °C) amounts to 0.15 mmol/g. |
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ISSN: | 0040-5760 1573-935X |
DOI: | 10.1007/s11237-011-9213-y |