A high complex anchored on a carbonaceous support

A high complex anchored on a carbonaceous support

The (Z)/(E) ratio was analyzed for the 3-hexyne semi-hydrogenation at 275, 290 and 303 K. [RhCl(N[H.sub.2] [[(C[H.sub.2]).sub.12]C[H.sub.3]).sub.3] pure and supported on a carbonaceous material were used as catalysts. The supported complex showed high values of conversion and selectivity, and its be...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Catalysis letters 2012-02, Vol.142 (2), p.231
Hauptverfasser: Liprandi, Domingo A, Cagnola, Edgardo A, Paredes, Jose F, Badano, Juan M, Quiroga, Monica E
Format: Artikel
Sprache:eng
Schlagworte:
Analysis
Hydrogenation
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The (Z)/(E) ratio was analyzed for the 3-hexyne semi-hydrogenation at 275, 290 and 303 K. [RhCl(N[H.sub.2] [[(C[H.sub.2]).sub.12]C[H.sub.3]).sub.3] pure and supported on a carbonaceous material were used as catalysts. The supported complex showed high values of conversion and selectivity, and its behaviour was much better than the Lindlar catalyst used as a reference.
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-011-0761-5