Synthesis of macrocycles with one and more ent-beyerane skeletons based on the diterpenoid isosteviol
Macrocycles with one and more ent -beyerane skeletons were prepared by the reaction of 16,19-dihydroxyent-beyerane with several dibasic carboxylic acid chlorides. The structures of the synthesized compounds, namely, the number of ent -beyerane skeletons in the macrocycle, depended on the length of t...
Gespeichert in:
| Veröffentlicht in: | Chemistry of natural compounds 2011-07, Vol.47 (3), p.422-427 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | Macrocycles with one and more
ent
-beyerane skeletons were prepared by the reaction of 16,19-dihydroxyent-beyerane with several dibasic carboxylic acid chlorides. The structures of the synthesized compounds, namely, the number of
ent
-beyerane skeletons in the macrocycle, depended on the length of the polymethylene chain in the acid chloride. The molecular structures of two of the synthesized macrocycles were establishedby x-ray crystal structures. |
|---|---|
| ISSN: | 0009-3130 1573-8388 |
| DOI: | 10.1007/s10600-011-9949-6 |