Sulfenyl halides in the synthesis of heterocycles. 4. Heterocyclization in reactions of alkenes with sulfenylating reagents based on di(2-pyridyl) disulfide

Sulfenyl halides in the synthesis of heterocycles. 4. Heterocyclization in reactions of alkenes with sulfenylating reagents based on di(2-pyridyl) disulfide

Sulfenylating reagents have been obtained by the action of sulfuryl chloride or antimony pentachloride on di(2-pyridyl) disulfide. Their interaction with alkenes proceeds as addition-cyclization with ring closure by the nitrogen atom of the pyridine fragment of the sulfur-containing electrophile wit...

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Veröffentlicht in:Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2012-10, Vol.48 (7), p.1098-1104
Hauptverfasser: Borisov, A. V., Matsulevich, Zh. V., Osmanov, V. K., Borisova, G. N., Mammadova, G. Z., Maharramov, A. M., Khrustalev, V. N.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical tests and reagents
Chemistry
Chemistry and Materials Science
Chlorides
Dichloropropane
Nitrogen
Olefins
Organic Chemistry
Pharmacy
Pyridine
Sulfur compounds
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Zusammenfassung:Sulfenylating reagents have been obtained by the action of sulfuryl chloride or antimony pentachloride on di(2-pyridyl) disulfide. Their interaction with alkenes proceeds as addition-cyclization with ring closure by the nitrogen atom of the pyridine fragment of the sulfur-containing electrophile with the formation of 2,3-dihydro[1,3]thiazolo[3,2- a ]pyridinium derivatives.
ISSN:0009-3122
1573-8353
DOI:10.1007/s10593-012-1104-1