Influence of dehydration on the electron spin resonance in the [Cu.sub.3][[W[.sub.2] x 8[H.sub.2]O molecular magnet
The influence of dehydration on the electron spin resonance spectra in the [Cu.sub.3][[W[(CN[).sub.8]].sub.2][(pyrimidine).sub.2] x 8[H.sub.2]O molecular magnet has been found. It has been established that two ferromagnetic phases with the Curie temperatures of ~12-17 and ~50 K, which correspond to...
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Veröffentlicht in: | Physics of the solid state 2013-05, Vol.55 (5), p.990 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The influence of dehydration on the electron spin resonance spectra in the [Cu.sub.3][[W[(CN[).sub.8]].sub.2][(pyrimidine).sub.2] x 8[H.sub.2]O molecular magnet has been found. It has been established that two ferromagnetic phases with the Curie temperatures of ~12-17 and ~50 K, which correspond to two different lines of the ferromagnetic resonance, are present in crystals. Dehydration leads to increasing the Curie temperature of the low-temperature phase from 12 to 17 K and to varying the temperature dependences of the spectrum parameters of the high-temperature phase (the resonant field and the width line). |
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ISSN: | 1063-7834 1090-6460 |
DOI: | 10.1134/S1063783413050168 |