Fully Printed Flexible Chemiresistors with Tunable Selectivity Based on Gold Nanoparticles

This study presents a method for printing flexible chemiresistors comprising thin film transducers based on cross-linked gold nanoparticles (GNPs). First, interdigitated silver paste electrodes are printed onto polyimide (PI) foil via dispenser printing. Second, coatings of GNPs and dithiol/monothio...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Hauptverfasser:	Ketelsen, Bendix, Tjarks, Patrick P, Schlicke, Hendrik, Liao, Ying-Chih, Vossmeyer, Tobias
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemiresistor dispenser flexible gold Inkjet nanoparticle printing sensor
Online-Zugang:	Volltext bestellen
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page
container_issue
container_start_page
container_title
container_volume
creator	Ketelsen, Bendix Tjarks, Patrick P Schlicke, Hendrik Liao, Ying-Chih Vossmeyer, Tobias
description	This study presents a method for printing flexible chemiresistors comprising thin film transducers based on cross-linked gold nanoparticles (GNPs). First, interdigitated silver paste electrodes are printed onto polyimide (PI) foil via dispenser printing. Second, coatings of GNPs and dithiol/monothiol blends are inkjet-printed onto these electrode structures. 1,9-Nonanedithiol (9DT) is used as cross-linking agent and a variety of monothiols are added to tune the sensors’ chemical selectivity. When dosing these sensors with different analyte vapors (n-octane, toluene, 4-methyl-2-pentanone, 1-butanol, 1-propanol, ethanol, water; concentration range: 25–2000 ppm) they show fully reversible responses with short response and recovery times. The response isotherms follow a first-order Langmuir model, and their initial slopes reveal sensitivities of up to 4.5 × 10−5 ppm−1. Finally, it is demonstrated that arrays of printed sensors can be used to clearly discern analytes of different polarity.
doi_str_mv	10.3390/chemosensors8040116
format	Article
fullrecord	<record><control><sourceid>fraunhofer_E3A</sourceid><recordid>TN_cdi_fraunhofer_primary_oai_fraunhofer_de_N_618505</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>oai_fraunhofer_de_N_618505</sourcerecordid><originalsourceid>FETCH-fraunhofer_primary_oai_fraunhofer_de_N_6185053</originalsourceid><addsrcrecordid>eNqdi70OgjAURrs4GPUJXPoCagk_wVUiOhETmVyaK1zCTUpL2qLy9mLi4Oz0Jec7h7F1ILZhuBe7qsXOONTOWJeKSARBMme3fFBq5BdL2mPNc4Uvuivk2SSTRUfOTzp_km95OWj4fFdUWHl6kB_5AdyUGc1PRtW8AG16sJ4qhW7JZg0oh6vvLliUH8vsvGksDLo1DVrZW-rAjtIAyR9coyxkEqSxiMM_szeeg1T0</addsrcrecordid><sourcetype>Institutional Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Fully Printed Flexible Chemiresistors with Tunable Selectivity Based on Gold Nanoparticles</title><source>Fraunhofer-ePrints</source><creator>Ketelsen, Bendix ; Tjarks, Patrick P ; Schlicke, Hendrik ; Liao, Ying-Chih ; Vossmeyer, Tobias</creator><creatorcontrib>Ketelsen, Bendix ; Tjarks, Patrick P ; Schlicke, Hendrik ; Liao, Ying-Chih ; Vossmeyer, Tobias</creatorcontrib><description>This study presents a method for printing flexible chemiresistors comprising thin film transducers based on cross-linked gold nanoparticles (GNPs). First, interdigitated silver paste electrodes are printed onto polyimide (PI) foil via dispenser printing. Second, coatings of GNPs and dithiol/monothiol blends are inkjet-printed onto these electrode structures. 1,9-Nonanedithiol (9DT) is used as cross-linking agent and a variety of monothiols are added to tune the sensors’ chemical selectivity. When dosing these sensors with different analyte vapors (n-octane, toluene, 4-methyl-2-pentanone, 1-butanol, 1-propanol, ethanol, water; concentration range: 25–2000 ppm) they show fully reversible responses with short response and recovery times. The response isotherms follow a first-order Langmuir model, and their initial slopes reveal sensitivities of up to 4.5 × 10−5 ppm−1. Finally, it is demonstrated that arrays of printed sensors can be used to clearly discern analytes of different polarity.</description><identifier>DOI: 10.3390/chemosensors8040116</identifier><language>eng</language><subject>Chemiresistor ; dispenser ; flexible ; gold ; Inkjet ; nanoparticle ; printing ; sensor</subject><creationdate>2020</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,776,27837</link.rule.ids><linktorsrc>$$Uhttp://publica.fraunhofer.de/documents/N-618505.html$$EView_record_in_Fraunhofer-Gesellschaft$$FView_record_in_$$GFraunhofer-Gesellschaft$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Ketelsen, Bendix</creatorcontrib><creatorcontrib>Tjarks, Patrick P</creatorcontrib><creatorcontrib>Schlicke, Hendrik</creatorcontrib><creatorcontrib>Liao, Ying-Chih</creatorcontrib><creatorcontrib>Vossmeyer, Tobias</creatorcontrib><title>Fully Printed Flexible Chemiresistors with Tunable Selectivity Based on Gold Nanoparticles</title><description>This study presents a method for printing flexible chemiresistors comprising thin film transducers based on cross-linked gold nanoparticles (GNPs). First, interdigitated silver paste electrodes are printed onto polyimide (PI) foil via dispenser printing. Second, coatings of GNPs and dithiol/monothiol blends are inkjet-printed onto these electrode structures. 1,9-Nonanedithiol (9DT) is used as cross-linking agent and a variety of monothiols are added to tune the sensors’ chemical selectivity. When dosing these sensors with different analyte vapors (n-octane, toluene, 4-methyl-2-pentanone, 1-butanol, 1-propanol, ethanol, water; concentration range: 25–2000 ppm) they show fully reversible responses with short response and recovery times. The response isotherms follow a first-order Langmuir model, and their initial slopes reveal sensitivities of up to 4.5 × 10−5 ppm−1. Finally, it is demonstrated that arrays of printed sensors can be used to clearly discern analytes of different polarity.</description><subject>Chemiresistor</subject><subject>dispenser</subject><subject>flexible</subject><subject>gold</subject><subject>Inkjet</subject><subject>nanoparticle</subject><subject>printing</subject><subject>sensor</subject><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFSUM</sourceid><sourceid>E3A</sourceid><recordid>eNqdi70OgjAURrs4GPUJXPoCagk_wVUiOhETmVyaK1zCTUpL2qLy9mLi4Oz0Jec7h7F1ILZhuBe7qsXOONTOWJeKSARBMme3fFBq5BdL2mPNc4Uvuivk2SSTRUfOTzp_km95OWj4fFdUWHl6kB_5AdyUGc1PRtW8AG16sJ4qhW7JZg0oh6vvLliUH8vsvGksDLo1DVrZW-rAjtIAyR9coyxkEqSxiMM_szeeg1T0</recordid><startdate>2020</startdate><enddate>2020</enddate><creator>Ketelsen, Bendix</creator><creator>Tjarks, Patrick P</creator><creator>Schlicke, Hendrik</creator><creator>Liao, Ying-Chih</creator><creator>Vossmeyer, Tobias</creator><scope>AFSUM</scope><scope>E3A</scope></search><sort><creationdate>2020</creationdate><title>Fully Printed Flexible Chemiresistors with Tunable Selectivity Based on Gold Nanoparticles</title><author>Ketelsen, Bendix ; Tjarks, Patrick P ; Schlicke, Hendrik ; Liao, Ying-Chih ; Vossmeyer, Tobias</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-fraunhofer_primary_oai_fraunhofer_de_N_6185053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Chemiresistor</topic><topic>dispenser</topic><topic>flexible</topic><topic>gold</topic><topic>Inkjet</topic><topic>nanoparticle</topic><topic>printing</topic><topic>sensor</topic><toplevel>online_resources</toplevel><creatorcontrib>Ketelsen, Bendix</creatorcontrib><creatorcontrib>Tjarks, Patrick P</creatorcontrib><creatorcontrib>Schlicke, Hendrik</creatorcontrib><creatorcontrib>Liao, Ying-Chih</creatorcontrib><creatorcontrib>Vossmeyer, Tobias</creatorcontrib><collection>Fraunhofer-ePrints - FT</collection><collection>Fraunhofer-ePrints</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Ketelsen, Bendix</au><au>Tjarks, Patrick P</au><au>Schlicke, Hendrik</au><au>Liao, Ying-Chih</au><au>Vossmeyer, Tobias</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fully Printed Flexible Chemiresistors with Tunable Selectivity Based on Gold Nanoparticles</atitle><date>2020</date><risdate>2020</risdate><abstract>This study presents a method for printing flexible chemiresistors comprising thin film transducers based on cross-linked gold nanoparticles (GNPs). First, interdigitated silver paste electrodes are printed onto polyimide (PI) foil via dispenser printing. Second, coatings of GNPs and dithiol/monothiol blends are inkjet-printed onto these electrode structures. 1,9-Nonanedithiol (9DT) is used as cross-linking agent and a variety of monothiols are added to tune the sensors’ chemical selectivity. When dosing these sensors with different analyte vapors (n-octane, toluene, 4-methyl-2-pentanone, 1-butanol, 1-propanol, ethanol, water; concentration range: 25–2000 ppm) they show fully reversible responses with short response and recovery times. The response isotherms follow a first-order Langmuir model, and their initial slopes reveal sensitivities of up to 4.5 × 10−5 ppm−1. Finally, it is demonstrated that arrays of printed sensors can be used to clearly discern analytes of different polarity.</abstract><doi>10.3390/chemosensors8040116</doi><oa>free_for_read</oa></addata></record>
fulltext	fulltext_linktorsrc
identifier	DOI: 10.3390/chemosensors8040116
ispartof
issn
language	eng
recordid	cdi_fraunhofer_primary_oai_fraunhofer_de_N_618505
source	Fraunhofer-ePrints
subjects	Chemiresistor dispenser flexible gold Inkjet nanoparticle printing sensor
title	Fully Printed Flexible Chemiresistors with Tunable Selectivity Based on Gold Nanoparticles
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T23%3A43%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-fraunhofer_E3A&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fully%20Printed%20Flexible%20Chemiresistors%20with%20Tunable%20Selectivity%20Based%20on%20Gold%20Nanoparticles&rft.au=Ketelsen,%20Bendix&rft.date=2020&rft_id=info:doi/10.3390/chemosensors8040116&rft_dat=%3Cfraunhofer_E3A%3Eoai_fraunhofer_de_N_618505%3C/fraunhofer_E3A%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true