An equilibrium and stability study of delta 1-pyrroline

Several properties of the compound 3,4-dihydro-2H-pyrrole (delta-1-pyrroline), which has been reported as a component of the male-produced Mediterranean fruit fly pheromone, have been determined by [H1]- and [13C]nuclear magnetic resonance spectroscopy. The stability of delta-1-pyrroline in several...

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Veröffentlicht in:Journal of chemical ecology 1992-09, Vol.18 (9)
Hauptverfasser: Baker, J.D, Heath, R.R, Millar, J.G
Format: Artikel
Sprache:eng
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Zusammenfassung:Several properties of the compound 3,4-dihydro-2H-pyrrole (delta-1-pyrroline), which has been reported as a component of the male-produced Mediterranean fruit fly pheromone, have been determined by [H1]- and [13C]nuclear magnetic resonance spectroscopy. The stability of delta-1-pyrroline in several solvents and at moderately elevated temperatures has been investigated, and it has been established that it exists as both a monomer and trimer in solution. Although equilibrium studies indicate that the trimer is thermodynamically more stable than the monomer in solution, only the monomer was found in the vapor phase based on infrared analysis
ISSN:0098-0331
1573-1561
DOI:10.1007/BF00993232