Hydrogen-bonding. 22. Characterization of soybean oil and prediction of activity coefficients in soybean oil from inverse gas chromatographic data

Previously reported results on twenty-two gaseous compounds with soybean oil as the stationary gas chromatographic phase have been used to characterize soybean oil in terms of dipolarity/polarizability, hydrogen-bond basicity and lipophilicity. The solubility of these gases in soybean oil has been f...

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Veröffentlicht in:Journal of the American Oil Chemists' Society 1992-12, Vol.69 (12), p.1236-1238
Hauptverfasser: Abraham, M.H. (University College London, London, United Kingdom), Whiting, G.S
Format: Artikel
Sprache:eng
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Zusammenfassung:Previously reported results on twenty-two gaseous compounds with soybean oil as the stationary gas chromatographic phase have been used to characterize soybean oil in terms of dipolarity/polarizability, hydrogen-bond basicity and lipophilicity. The solubility of these gases in soybean oil has been factored into components that show exactly the compound-soybean oil interactions that favor solubility. The same equation used to obtain this information also can be used to predict the gas chromatographic specific retention volume and then the weight-fraction activity coefficient for numerous other compounds on soybean oil, thus leading to predictions of the solubility behavior of these compounds as bulk liquids with soybean oil.
ISSN:0003-021X
1558-9331
DOI:10.1007/BF02637688