Synthetic study on a novel Asn-linked core structure: synthesis of a pentasaccharide alpha-D-Man-(1 leads to 3)-[alpha-D-Man-(1 leads to 6)]-beta-D-Man-(1 leads to 4)-[beta-D-glcNAc-(1 leads to 6)]-beta-D-GlcNAc leads to OMp1

Synthetic study on a novel Asn-linked core structure: synthesis of a pentasaccharide alpha-D-Man-(1 leads to 3)-[alpha-D-Man-(1 leads to 6)]-beta-D-Man-(1 leads to 4)-[beta-D-glcNAc-(1 leads to 6)]-beta-D-GlcNAc leads to OMp1

Synthesis of a pentasaccharide alpha-D-Man- (1 leads to 3)-[alpha-D-Man(1 leads to 6)]-beta-D-Man- (1 leads to 4)-[beta-D-GlcNAc(1 leads to 6)]-beta-D- GlcNAc leads to OMp (2) is described. A comparison between the 1H NMR data of 2 and those of a novel Asn-linked core structure 1 containing a new Gl...

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Veröffentlicht in:Carbohydrate research 1998, Vol.306 (4), p.539-544
Hauptverfasser: Guo, Z.W, Ito, Y, Nakahara, Y, Ogawa, T
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container_title Carbohydrate research
container_volume 306
creator Guo, Z.W
Ito, Y
Nakahara, Y
Ogawa, T
description Synthesis of a pentasaccharide alpha-D-Man- (1 leads to 3)-[alpha-D-Man(1 leads to 6)]-beta-D-Man- (1 leads to 4)-[beta-D-GlcNAc(1 leads to 6)]-beta-D- GlcNAc leads to OMp (2) is described. A comparison between the 1H NMR data of 2 and those of a novel Asn-linked core structure 1 containing a new GlcNAc residue suggests an alpha- D-configuration for the new linkage.
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title Synthetic study on a novel Asn-linked core structure: synthesis of a pentasaccharide alpha-D-Man-(1 leads to 3)-[alpha-D-Man-(1 leads to 6)]-beta-D-Man-(1 leads to 4)-[beta-D-glcNAc-(1 leads to 6)]-beta-D-GlcNAc leads to OMp1
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