Synthetic study on a novel Asn-linked core structure: synthesis of a pentasaccharide alpha-D-Man-(1 leads to 3)-[alpha-D-Man-(1 leads to 6)]-beta-D-Man-(1 leads to 4)-[beta-D-glcNAc-(1 leads to 6)]-beta-D-GlcNAc leads to OMp1
Synthesis of a pentasaccharide alpha-D-Man- (1 leads to 3)-[alpha-D-Man(1 leads to 6)]-beta-D-Man- (1 leads to 4)-[beta-D-GlcNAc(1 leads to 6)]-beta-D- GlcNAc leads to OMp (2) is described. A comparison between the 1H NMR data of 2 and those of a novel Asn-linked core structure 1 containing a new Gl...
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Veröffentlicht in: | Carbohydrate research 1998, Vol.306 (4), p.539-544 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Synthesis of a pentasaccharide alpha-D-Man- (1 leads to 3)-[alpha-D-Man(1 leads to 6)]-beta-D-Man- (1 leads to 4)-[beta-D-GlcNAc(1 leads to 6)]-beta-D- GlcNAc leads to OMp (2) is described. A comparison between the 1H NMR data of 2 and those of a novel Asn-linked core structure 1 containing a new GlcNAc residue suggests an alpha- D-configuration for the new linkage. |
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ISSN: | 0008-6215 1873-426X |