Monoacetalization of unprotected sucrose with citral and ionones

The monoacetalization of sucrose by citral, alpha-ionone and beta-ionone is reported. Geranial and neral sucrose acetals (E and Z isomers of citral acetals) are described. Optimization of the acidic catalysis afforded good yields of acetals directly from unprotected sucrose by transacetalization of...

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Veröffentlicht in:Journal of carbohydrate chemistry 1998, Vol.17 (1), p.129-142
Hauptverfasser: Salanski, P, Descotes, G, Bouchu, A, Queneau, Y
Format: Artikel
Sprache:eng
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Zusammenfassung:The monoacetalization of sucrose by citral, alpha-ionone and beta-ionone is reported. Geranial and neral sucrose acetals (E and Z isomers of citral acetals) are described. Optimization of the acidic catalysis afforded good yields of acetals directly from unprotected sucrose by transacetalization of dimethyl acetals in dimethylformamide. The influence of microwave irradiation on the reaction outcome was investigated.
ISSN:0732-8303
1532-2327
DOI:10.1080/07328309808005773