Highly stereoselective rearrangement of (E,E9-suspensolide to anastrephin and epianastrephin

Highly stereoselective rearrangement of (E,E9-suspensolide to anastrephin and epianastrephin

The facility of the title rearrangement has clear mechanistic implications for the major pathway in the biosynthetic production of anastrephin (2) and epianastrephin (3) in the male Anastrepha fruit fly species A. suspensa (Caribbean) and A. ludens (Mexican).

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Veröffentlicht in:Tetrahedron letters 1991, Vol.32 (39), p.5303-5304
Hauptverfasser: Battiste, M.A, Strekowski, L, Coxon, J.M, Wydra, R.L, Harden, D.B
Format: Artikel
Sprache:eng
Schlagworte:
Anastrepha ludens
Anastrepha suspensa
chemical reactions
sex pheromones
stereochemistry
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Zusammenfassung:The facility of the title rearrangement has clear mechanistic implications for the major pathway in the biosynthetic production of anastrephin (2) and epianastrephin (3) in the male Anastrepha fruit fly species A. suspensa (Caribbean) and A. ludens (Mexican).
ISSN:0040-4039
1873-3581