Alkaloids of thalictrum—XXIII : Four new aporphine-benzylisoquinoline dimeric alkaloids from thalictrum revolutum

Structures based on physical and chemical methods, are proposed for four new aporphine-ben-zylisoquinoline dimers. Thalirevolutine ( 1) and thalirevoline ( 2) are related to fetidine ( 5), the latter is isomeric with fetidine bearing the phenolic group at C-4″, and the former is O methylfetidine. Th...

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Veröffentlicht in:Tetrahedron 1977, Vol.33 (22), p.2919-2922
Hauptverfasser: Wu, W.-N., Beal, J.L., Doskotch, R.W.
Format: Artikel
Sprache:eng
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Zusammenfassung:Structures based on physical and chemical methods, are proposed for four new aporphine-ben-zylisoquinoline dimers. Thalirevolutine ( 1) and thalirevoline ( 2) are related to fetidine ( 5), the latter is isomeric with fetidine bearing the phenolic group at C-4″, and the former is O methylfetidine. Thalilutidine ( 3) is the C-6' phenolic analogue of thalicarpine ( 6), while thalilutine ( 4) is the C-3 phenolic analogue of adiantifoline ( 13).
ISSN:0040-4020
1464-5416
DOI:10.1016/0040-4020(77)88023-X