Synthesis, Purification, and Characterization of a [mu]-(1,3-Propanedithiolato)-Hexacarbonyldiiron

Synthesis, Purification, and Characterization of a [mu]-(1,3-Propanedithiolato)-Hexacarbonyldiiron

A project which exposes students to biologically important transition-metal chemistry is illustrated by taking an example of the iron-carbonyl compound, [mu]-(1,3-Propanedithiolaro)-hexa-carbonyldiiron as a structural model for an iron-only hydro-genase. The project provides the students with experi...

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Veröffentlicht in:Journal of chemical education 2007-05, Vol.84 (5)
1. Verfasser: Works, Carmen F
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
College Science
Inorganic Chemistry
Interdisciplinary Approach
Laboratory Experiments
Metallurgy
Science Experiments
Science Instruction
Spectroscopy
Undergraduate Study
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Zusammenfassung:A project which exposes students to biologically important transition-metal chemistry is illustrated by taking an example of the iron-carbonyl compound, [mu]-(1,3-Propanedithiolaro)-hexa-carbonyldiiron as a structural model for an iron-only hydro-genase. The project provides the students with experience of Schlenk line techniques, purification, and spectroscopic characterization of metal carbonyls.
ISSN:0021-9584