LIQUID/LIQUID CATALYTIC SWEETENING PROCESS

A liquid/liquid sweetening process for catalytically oxidizing mercaptans in a sour hydrocarbon fraction is improved by the addition of a quaternary ammonium compound to the alkaline solution which contains a metal chelate catalyst such as a metal phthalocyanine and which in combination with an oxid...

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Bibliographische Detailangaben
Hauptverfasser: SHEILA L. POLLASTRINI, ROBERT R. FRAME, BRYAN L. BENEDICT, JEFFREY C. BRICKER
Format: Patent
Sprache:eng
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Zusammenfassung:A liquid/liquid sweetening process for catalytically oxidizing mercaptans in a sour hydrocarbon fraction is improved by the addition of a quaternary ammonium compound to the alkaline solution which contains a metal chelate catalyst such as a metal phthalocyanine and which in combination with an oxidizing agent has been used in the prior art as the sweetening agent. A preferred type of quaternary ammonium compound is a surfactant quaternary ammonium compound. A synergistic effect between the quaternary ammonium compound and the metal chelate is observed.