NEW CRYSTALLINE ALUMINOSILICATE ZEOLITE CATALYST AND THE METHOD FOR MANUFACTURING THEREOF

A crystalline alumino-silicate ZKU-catalyst, comprising: a crystallized composition having the following molar ratios: SiO2/Al2O3 8-70 OH-/SiO2 0.2-1.6 H2O/SiO2 10-30 M/SiO2 0.2-1.7 R/SiO2 0.0086-0.20 R/R+M 0.0005-0.40 K2O/M2O 0.05-0.3 wherein R is a conditioning agent comprising a tetraalkyl ammoni...

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Bibliographische Detailangaben
Hauptverfasser:	YOSHINOBU TAKEGAMI, TOSHIHIRO KANIE, TOMOYUKI INUI, TAKAYUKI ISHIHARA, EIICHI ARAKI
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOUNDS THEREOF CRACKING HYDROCARBON OILS FUELS GENERAL METHODS OF ORGANIC CHEMISTRY INORGANIC CHEMISTRY LUBRICANTS METALLURGY MINERAL WAXES NON-METALLIC ELEMENTS ORGANIC CHEMISTRY PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	A crystalline alumino-silicate ZKU-catalyst, comprising: a crystallized composition having the following molar ratios: SiO2/Al2O3 8-70 OH-/SiO2 0.2-1.6 H2O/SiO2 10-30 M/SiO2 0.2-1.7 R/SiO2 0.0086-0.20 R/R+M 0.0005-0.40 K2O/M2O 0.05-0.3 wherein R is a conditioning agent comprising a tetraalkyl ammonium cation, the alkyl moieties of which are methyl or ethyl; and wherein M is an alkali metal ion. The composition is defined by its X-ray diffraction pattern. The catalyst is made by heating the composition to a temperature of from about 150.degree.C to about 270.degree.C; maintaining the composition at this temperature for a period of from about 0.5 to about 20 hours and forming a crystallized product thereby; further processing the crystallized product by filtering, washing and drying; and calcining the product at a temperature of from about 400.degree.C to about 600.degree.C for a period of from about 0.5 to about 5 hours. The composition can also be mixed with seed crystals such as .alpha.-alumina, kaoline, zeolite or porcelain powders. The catalyst has the advantages of superior catalytic activity, selectivity and long life.