PROCESS FOR PREPARING FORMIC ACID

Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and tertiary amine (I) is produced by combining tertiary amine (I) and a formic acid source, secondary components comprised therein are...

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Bibliographische Detailangaben
Hauptverfasser: TELES, Joaquim, Henrique, RITTINGER, Stefan, PASCHOLD, Jürgen, SCHNEIDER, Daniel, SCHÄFER, Martin, FRIES, Donata, Maria, BASSLER, Peter, MOHL, Klaus-Dieter
Format: Patent
Sprache:eng
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Zusammenfassung:Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid and tertiary amine (I) is produced by combining tertiary amine (I) and a formic acid source, secondary components comprised therein are separated off, formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, where the bottom output from the distillation apparatus is separated into two liquid phases, and the upper liquid phase is recirculated to the formic acid source and the lower liquid phase is recirculated to the separation of the secondary components and/or to the distillation apparatus, wherein low boilers are removed by distillation from the upper liquid phase and recirculated to the depleted stream.