PROCESS FOR THE OLIGOMERIZATION OF VINYL CHLORIDE

Polymerizatlon of vinyl chloride monomer, by either suspension or emulsion polymerization, optionally in the presence of a monoethylenically unsaturated comonomer, is carried out in the presence of a mixture of calcium and zinc acrylate. The presence of the calcium and zinc acrylate yield a more the...

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Bibliographische Detailangaben
Hauptverfasser: ANDERSON F.D, JUN-SHEN YU A
Format: Patent
Sprache:eng
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Zusammenfassung:Polymerizatlon of vinyl chloride monomer, by either suspension or emulsion polymerization, optionally in the presence of a monoethylenically unsaturated comonomer, is carried out in the presence of a mixture of calcium and zinc acrylate. The presence of the calcium and zinc acrylate yield a more thermally stable product and reduces the amount of polymer scale formation during polymerization. A further improvement in thermal stability is achieved by conducting the polymerization with the added presence of an epoxy compound containing a reactive vinyl or allyl group.