METHOD FOR PREPARING FOAMABLE ORGANO-SILICONE COMPOSITIONS
The present invention relates to a method which comprises mixing together an organosiloxane rubber, an organo-silicone cross-linking agent and a platinum catalyst. This method also comprises adding an additional catalyst in the shape of an inorganic cobalt compound having a cobalt content of 34 wt %...
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Zusammenfassung: | The present invention relates to a method which comprises mixing together an organosiloxane rubber, an organo-silicone cross-linking agent and a platinum catalyst. This method also comprises adding an additional catalyst in the shape of an inorganic cobalt compound having a cobalt content of 34 wt %. The organosiloxane rubber consists in alpha , omega -dihydroxypolydiorganosiloxanes of the general formula HO[R R SiO]nH which have a viscosity of 15 DIVIDED 300 P at 20 DEG C and a molecular weight of between 20000 and 65000. The letter n is an integer ranging from 270 to 870, while R and R represent aliphatic radicals comprising from 1 to 6 carbon atoms, phenyl, a chloromethyl group or a 3,3,3-trifluoropropyl group. The organo-silicone cross-linking agent consists in polyorganosiloxane hydrides of the general formula R 3SiO[R (H)SiO]m[R 2SiO]lSiR 3 which have a SiH-group content of between 0.35 and 1.80 wt.% and a molecular weight of between 50 and 200. R and R represent an alkyl radical comprising from 1 to 6 carbon atoms and m is an integer ranging from 1 to 20 while l is an integer ranging from 0 to 19, with the proviso that m + l = 20. The components are mixed together according to the following proportions: 100 parts by weight of organosiloxane rubber; from 8 to 15 parts by weight of organo-silicone cross-linking agent; (9,04 DIVIDED 8,94) 10 parts by weight of platinum catalyst; and 12 DIVIDED 22 parts by weight of additional catalyst.
Cette invention concerne un procédé qui consiste à mélanger un caoutchouc à base de siloxane organique, un agent de réticulation à base de silicone organique ainsi qu'un catalyseur à base de platine. Ce procédé consiste également à ajouter un catalyseur complémentaire qui consiste en un composé de cobalt inorganique ayant une teneur en cobalt de 34 % en poids. On utilise en qualité de caoutchouc à base de siloxane organique des alpha , omega -dihydroxypolydiorganosiloxanes qui correspondent à la formule générale HO[R R SiO]nH, et qui possèdent une viscosité de 15 DIVIDED 300 P à 20 DEG C ainsi qu'un poids moléculaire de 20000 à 65000. La lettre n représente un nombre entier de 270 à 870, tandis que R et R représentent des radicaux aliphatiques comportant de 1 à 6 atomes de carbone, phényle, un groupe chlorométhyle ou un groupe 3,3,3-trifluoropropyle. On utilise en qualité d'agent de réticulation à base de silicone organique des hydrures de polyorganosiloxanes qui correspondent à la formule générale R 3SiO[R (H)SiO]m[ |
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