RECYCLATE POLYETHYLENE COMPOSITION WITH IMPROVED MECHANICAL AND OPTICAL PROPERTIES

The present invention relates to a mixed-plastic recyclate polyethylene composition having a melt flow rate (ISO 1133, 2.16 kg, 190 °C) of from 0.1 to 1.5 g/10 min; and a density of from 938 to 985 kg/m3, and comprising 35 wt.-% or more of a recycled polyethylene fraction (rPE), wherein the mixed-pl...

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Bibliographische Detailangaben
Hauptverfasser: LIU, Yi, RIBARITS, Elisabeth, BRAUN, Hermann
Format: Patent
Sprache:eng ; fre
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Zusammenfassung:The present invention relates to a mixed-plastic recyclate polyethylene composition having a melt flow rate (ISO 1133, 2.16 kg, 190 °C) of from 0.1 to 1.5 g/10 min; and a density of from 938 to 985 kg/m3, and comprising 35 wt.-% or more of a recycled polyethylene fraction (rPE), wherein the mixed-plastic recyclate polyethylene composition has (a) a total amount of ethylene units (C2 units) of at least 95.0 wt.-%, as measured by 13C-NMR of the d2-tetrachloroethylene soluble fraction; (b) a total amount of continuous C3 units originating from polypropylene (PP) in an amount of from 0 to 3.0 wt.-%, determined by quantitative 13C{1H} -NMR measurement of the soluble fraction; and (c) an environmental stress crack resistance (ESCR) according to the Bell test, in accordance with IEC 60811-406, method B of at least 1000 h failure time, wherein the mixed-plastic recyclate polyethylene composition further comprises at least one virgin polyethylene component (B), optionally blended with carbon black, and optionally a virgin polyethylene component (B1), different from virgin polyethylene component (B), optionally blended with carbon black, wherein the mixed-plastic recyclate polyethylene composition has a tear resistance, determined according to BS 6469 section 99.1 of at least 24 N/mm. Such a mixed-plastic recyclate polyethylene composition has high purity in terms of polyethylene content, low content of contaminants, high homogeneity, improved mechanical properties, and good optical properties. The present invention further relates to a method for its preparation, to the above recycled polyethylene fraction (rPE), obtainable or obtained by a method of recycling a mixed-plastic recycling stream, to an article made from the above mixed-plastic recyclate polyethylene composition, and to the use of the above mixed-plastic recyclate polyethylene composition for wire and cable applications. La présente invention concerne une composition de polyéthylène de recyclage mixte-plastique ayant un indice de fluidité (ISO 1133, 2,16 kg, 190°C) de 0,1 à 1,5 g/10 min ; et une masse volumique de 938 à 985 kg/m3, et comprenant 35% en poids ou plus d'une fraction de polyéthylène recyclé (rPE), la composition de polyéthylène de recyclage mixte-plastique ayant (a) une quantité totale d'unités éthylène (unités C2) d'au moins 95,0% en poids, telle que mesurée par RMN 13C de la fraction soluble dans d2-tétrachloroéthylène ; (b) une quantité totale d'unités C3 continues provenant de polyprop