LITHIUM SECONDARY BATTERY COMPRISING LITHIUM-RICH MANGANESE-BASED OXIDE, AND MANUFACTURING METHOD THEREFOR
The present invention relates to a lithium secondary battery, and a manufacturing method therefor, the lithium secondary battery comprising: a cathode comprising a lithium-rich manganese-based oxide in which the amount of manganese in an entire metal that excludes lithium exceeds 50 mol%, and the ra...
Gespeichert in:
Hauptverfasser: | , |
---|---|
Format: | Patent |
Sprache: | eng ; fre ; kor |
Schlagworte: | |
Online-Zugang: | Volltext bestellen |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | The present invention relates to a lithium secondary battery, and a manufacturing method therefor, the lithium secondary battery comprising: a cathode comprising a lithium-rich manganese-based oxide in which the amount of manganese in an entire metal that excludes lithium exceeds 50 mol%, and the ratio (Li/Me) of the moles of lithium to the moles of in the entire metal that excludes lithium exceeds 1; an anode; and an electrolyte, wherein, when the total discharge curve area is 100% in a dQ/dV graph obtained by differentiating the graphs of voltage V and battery discharge capacity Q measured while charging the lithium secondary battery to 4.6 V at 0.1 C, and then discharging same to 2.0 V at 0.1 C, the discharge curve area in the voltage range of 2.0-3.5 V is 35% or less.
La présente invention concerne une batterie secondaire au lithium, et son procédé de fabrication, la batterie secondaire au lithium comprenant : une cathode comprenant un oxyde à base de manganèse riche en lithium dans lequel la quantité de manganèse dans un métal entier qui exclut le lithium dépasse 50 % en mole, et le rapport (Li/Me) des moles de lithium sur les moles dans le métal entier qui exclut le lithium dépasse 1 ; une anode ; et un électrolyte ; lorsque la zone de courbe de décharge totale est de 100 % dans un graphe dQ/dV obtenu par différenciation des graphes de tension V et de capacité de décharge de batterie Q mesurée tout en chargeant la batterie secondaire au lithium sur 4,6 V à 0,1 C, puis en déchargeant celle-ci sur 2,0 V à 0,1 C, la zone de courbe de décharge dans la plage de tension de 2,0 à 3,5 V est de 35 % ou moins.
본 발명은, 리튬을 제외한 전체 금속 중 망간의 함량이 50몰%를 초과하고, 리튬을 제외한 전체 금속의 몰수에 대한 리튬의 몰수의 비(Li/Me)가 1을 초과하는 과리튬 망간계 산화물을 포함하는 양극, 음극, 및 전해질을 포함하는 리튬 이차 전지이되, 상기 리튬 이차 전지를 0.1C으로 4.6V까지 충전한 후, 0.1C으로 2.0V까지 방전하면서 측정한 전압 V와 전지 방전 용량 Q의 그래프를 미분하여 얻어진 dQ/dV 그래프에서 전체 방전 커브 면적을 100%라 할 때, 2.0 ~ 3.5V 전압 범위에서의 방전 커브 면적이 35% 이하인 리튬 이차 전지 및 그 제조 방법에 관한 것이다. |
---|