SECONDARY BATTERY COMPRISING LOW-EFFICIENCY CATHODE
According to the present embodiment, provided is a secondary battery comprising a cathode, an anode, and a separator interposed between the cathode and the anode. The cathode includes a cathode mixture layer formed on at least one surface of a cathode current collector, the cathode mixture layer com...
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Zusammenfassung: | According to the present embodiment, provided is a secondary battery comprising a cathode, an anode, and a separator interposed between the cathode and the anode. The cathode includes a cathode mixture layer formed on at least one surface of a cathode current collector, the cathode mixture layer comprises a cathode active material, and the cathode active material includes a lithium transition metal oxide doped with a dopant and having a molar ratio of Ni of 88% or more with respect to the total moles of transition metals excluding Li. The anode includes an anode mixture layer formed on at least one surface of an anode current collector, the anode mixture layer comprises an anode active material, and the anode active material includes a silicon-based active material. The cathode has a ratio (initial efficiency) of initial discharge capacity to initial charge capacity that is 85% to 89% in a battery having lithium as a counter electrode.
Selon un mode de réalisation, l'invention concerne une batterie secondaire comprenant une cathode, une anode et un séparateur intercalé entre celles-ci. La cathode comporte, formée sur au moins une surface d'un collecteur de courant de cathode, une couche de mélange de cathode comprenant un matériau actif de cathode comportant un oxyde de métal de transition de lithium (Li) dopé par un dopant et ayant un rapport molaire de nickel (Ni) supérieur ou égal à 88 % en moles du total de métaux de transition hors Li. L'anode comporte, formée sur au moins une surface d'un collecteur de courant d'anode, une couche de mélange d'anode comprenant un matériau actif d'anode comportant un matériau actif à base de silicium (Si). La cathode présente un rapport (rendement initial) de capacité initiale de décharge à une capacité initiale de charge compris entre 85 et 89 % dans une batterie à contre-électrode en Li.
본 실시예에 따르면, 양극, 음극 및 상기 양극과 상기 음극 사이에 개재되는 분리막을 포함하는 이차전지로서, 상기 양극은 양극 집전체의 적어도 일면에 양극 합제층이 형성되어 있고, 상기 양극 합제층은 양극 활물질을 포함하며, 상기 양극 활물질은 도펀트가 도핑되어 있고 Ni의 몰비가 Li을 제외한 전이금속 총 몰 기준으로 88% 이상인 리튬 전이금속 산화물을 포함하며, 상기 음극은 음극 집전체의 적어도 일면에 음극 합제층이 형성되어 있고, 상기 음극 합제층은 음극 활물질을 포함하며, 상기 음극 활물질은 실리콘계 활물질을 포함하고, 상기 양극은 리튬을 대극으로 한 전지에서의 초기 충전 용량 대비 초기 방전 용량의 비율(초기 효율)이 85% 내지 89%인 이차전지가 제공된다. |
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