MULTI-COPPER CLUSTER AND PREPARATION METHOD THEREFOR

The present application provides a multi-copper cluster having a molecular formula of [Cu8(X)6Y6]Z2, in which X is a ligand, Y is H- or D-, Z is a monovalent anion, and X includes a phosphorus atom and a plurality of polycyclic ring groups connected to the phosphorus atom. The present application fu...

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Bibliographische Detailangaben
Hauptverfasser:	WANG, Quanming, YUAN, Shangfu
Format:	Patent
Sprache:	chi ; eng ; fre
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMISTRY METALLURGY ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:	The present application provides a multi-copper cluster having a molecular formula of [Cu8(X)6Y6]Z2, in which X is a ligand, Y is H- or D-, Z is a monovalent anion, and X includes a phosphorus atom and a plurality of polycyclic ring groups connected to the phosphorus atom. The present application further provides a preparation method for the multi-copper cluster, comprising the following steps: providing Cu(CH3CN)4Z and X; dissolving the Cu(CH3CN)4Z and X in a first solvent, and performing a reaction by means of stirring to obtain a first solution; and adding a compound containing negative valence hydrogen or deuterium to the first solution to obtain a third solution containing the multi-copper cluster. La présente invention concerne un agrégat multi-cuivre ayant une formule moléculaire de [Cu8(X)6Y6]Z2, dans laquelle X est un ligand, Y est H- ou D-, Z est un anion monovalent, et X comprend un atome de phosphore et une pluralité de groupes à noyaux polycycliques reliés à l'atome de phosphore. La présente inve