FIBER COATINGS WITH LOW MODULUS AND HIGH CRITICAL STRESS

Fiber coatings with low Young's modulus, high tear strength, and/or high critical stress are realized with coating compositions that include an oligomeric material formed from an isocyanate, a hydroxy acrylate compound and a polyol. The oligomeric material includes a polyether urethane acrylate...

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Hauptverfasser: TANDON, Pushkar, CHEN, Yangbin, KOUZMINA, Inna Igorevna, DEROSA, Michael Edward, CHIEN, Ching-Kee, TANDON, Ruchi
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CHEN, Yangbin
KOUZMINA, Inna Igorevna
DEROSA, Michael Edward
CHIEN, Ching-Kee
TANDON, Ruchi
description Fiber coatings with low Young's modulus, high tear strength, and/or high critical stress are realized with coating compositions that include an oligomeric material formed from an isocyanate, a hydroxy acrylate compound and a polyol. The oligomeric material includes a polyether urethane acrylate and a di-adduct compound. The reaction mixture used to form the oligomeric material includes a molar ratio of isocyanate:hydroxy acrylate:polyol of n:m:p, where when p is 2, n is in the range from 3.0 to 5.0 and m is in the range from 1.50n - 3 to 2.50n - 5. Control of the n:m:p ratio leads to compositions that, when cured, provide coatings and cured products having high critical stress, high tear strength, and a high ratio of tear strength to Young's modulus. L'invention concerne des revêtements de fibres présentant un faible module d'Young, une résistance élevée à la déchirure et/ou une résistance critique élevée, réalisés à l'aide de compositions de revêtement qui comprennent un matériau oligomère formé à partir d'un isocyanate, d'un composé hydroxy acrylate et d'un polyol. Le matériau oligomère comprend un acrylate de polyéther-uréthanne et un composé di-adduit. Le mélange réactionnel utilisé pour former le matériau oligomère comprend une proportion en moles isocyanate:hydroxy acrylate:polyol de n:m:p, où, quand p vaut 2, n est compris dans la plage de 3,0 à 5,0, et m est compris dans la plage de 1,50n-3 à 2,50n-5. La régulation de la proportion n:m:p conduit à des compositions qui, après durcissement, donnent des revêtements et des produits durcis présentant une résistance critique élevée, une résistance élevée au cisaillement et un rapport élevé entre la résistance au cisaillement et le module d'Young.
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The oligomeric material includes a polyether urethane acrylate and a di-adduct compound. The reaction mixture used to form the oligomeric material includes a molar ratio of isocyanate:hydroxy acrylate:polyol of n:m:p, where when p is 2, n is in the range from 3.0 to 5.0 and m is in the range from 1.50n - 3 to 2.50n - 5. Control of the n:m:p ratio leads to compositions that, when cured, provide coatings and cured products having high critical stress, high tear strength, and a high ratio of tear strength to Young's modulus. L'invention concerne des revêtements de fibres présentant un faible module d'Young, une résistance élevée à la déchirure et/ou une résistance critique élevée, réalisés à l'aide de compositions de revêtement qui comprennent un matériau oligomère formé à partir d'un isocyanate, d'un composé hydroxy acrylate et d'un polyol. Le matériau oligomère comprend un acrylate de polyéther-uréthanne et un composé di-adduit. 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subjects ADHESIVES
CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUSENAMELS
CHEMICAL PAINT OR INK REMOVERS
CHEMISTRY
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS
COMPOSITIONS BASED THEREON
CORRECTING FLUIDS
DYES
FILLING PASTES
GLASS
INKS
JOINING GLASS TO GLASS OR OTHER MATERIALS
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
MINERAL OR SLAG WOOL
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
OPTICAL ELEMENTS, SYSTEMS, OR APPARATUS
OPTICS
ORGANIC MACROMOLECULAR COMPOUNDS
PAINTS
PASTES OR SOLIDS FOR COLOURING OR PRINTING
PHYSICS
POLISHES
SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS,MINERALS OR SLAGS
SURFACE TREATMENT OF GLASS
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF MATERIALS THEREFOR
WOODSTAINS
title FIBER COATINGS WITH LOW MODULUS AND HIGH CRITICAL STRESS
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