COMPOSITIONS AND METHODS FOR SELECTIVE OLIGOMERIZATION COMPRISING METAL ORGANIC FRAMEWORKS

COMPOSITIONS AND METHODS FOR SELECTIVE OLIGOMERIZATION COMPRISING METAL ORGANIC FRAMEWORKS

Compositions and methods for selective olefin (e.g., ethylene) oligomerization comprising metal organic frameworks (MOFs) are generally provided In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two unsaturated N-heterocycli...

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Bibliographische Detailangaben
Hauptverfasser: DINCA, Mircea, BROZEK, Carl, K, METZGER, Eric, D
Format: Patent
Sprache:eng ; fre
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
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Zusammenfassung:Compositions and methods for selective olefin (e.g., ethylene) oligomerization comprising metal organic frameworks (MOFs) are generally provided In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two unsaturated N-heterocyclic aromatic groups arranged about an organic core. L'invention concerne des compositions et des procédés pour l'oligomérisation sélective d'oléfines (par ex. d'éthylène) comprenant des réseaux organométalliques (MOF). Dans certains modes de réalisation, un réseau organométallique comporte une pluralité d'ions métalliques chacun coordonné avec au moins un ligand comprenant au moins deux groupes aromatiques N-hétérocycliques insaturés agencés autour d'un noyau organique.