PHOTOCATALYTIC NANOCOMPOSITE STRUCTURED WITH BORON

A photocatalytic inorganic-organic hybrid composite material structured with boron and its preparation, comprising (a) particles composed of (a.1) nanoparticles (NPs) with = 1 of dimensions = 20 nm of at least one metal oxide being in particular TiO2 alone or TiO2 mixed with oxides of = 1 metals sel...

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Hauptverfasser: CELIKER, GULSEN, CELIKER, HUSEYIN, DEMIR, HILMI VOLKAN
Format: Patent
Sprache:eng ; fre
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Zusammenfassung:A photocatalytic inorganic-organic hybrid composite material structured with boron and its preparation, comprising (a) particles composed of (a.1) nanoparticles (NPs) with = 1 of dimensions = 20 nm of at least one metal oxide being in particular TiO2 alone or TiO2 mixed with oxides of = 1 metals selected from Zn, Al, Tl and Zr, (a.2) in particular particles of boron oxide or boron particles or clusters resulting from H3BO3 or B(OR)3, (a.3) a network made of condensation products of in particular alcohols, silanes and metal(loid) alkoxides, the metals being = 1 of Ti, Tl, Zn, Zr, Al, the metalloids being = 1 of Si, B, Sb; said network encapsulating the particles (a.2), said network including -O- bridges between the NPs (a.1) and the particles (a.2); (b) at least one resin, in particular an acrylic resin, optionally chemically modified by silane(s), siloxane(s) and/or silane coupling agents. These materials show enhanced UV and visible activity. L'invention concerne un nanocomposite hybride inorganique-organique fonctionnel structuré avec du bore. A l'aide de la présente invention, un matériau nanométrique est obtenu, lequel présente une activité améliorée dans la région visible et UV et dans lequel des combinaisons de nanoparticules de métal-oxyde avec des composés de bore sont utilisées.