HYDROFORMYLATION PROCESS WITH IMPROVED ISO-SELECTIVITY

HYDROFORMYLATION PROCESS WITH IMPROVED ISO-SELECTIVITY

Disclosed is a process for hydroformylation of a-olefin wherein said a-olefm is reacted with carbon monoxide or carbon monoxide and hydrogen and/or a reducing agent in presence of a catalyst complex based on a rhodium precursor and a ligand mixture comprising at least 1% by weight of triphenylphosph...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Hauptverfasser: KUNNAS, JONI, HARTEVA, MERJA, KARVINEN, ESKO, LEHTONEN, JUHA
Format: Patent
Sprache:eng ; fre
Schlagworte:
ACYCLIC OR CARBOCYCLIC COMPOUNDS
ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
APPARATUS THEREFOR
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
Online-Zugang:Volltext bestellen
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Disclosed is a process for hydroformylation of a-olefin wherein said a-olefm is reacted with carbon monoxide or carbon monoxide and hydrogen and/or a reducing agent in presence of a catalyst complex based on a rhodium precursor and a ligand mixture comprising at least 1% by weight of triphenylphosphine and at least 5% by weight of diphenylcyclohexylphosphine, tris-(o-tolyl)phosphine, tris-(p-tolyl)phosphine or (2-methyl- phenyl)diphenylphosphine. L'invention concerne un procédé destiné à l'hydroformylation d'une alpha oléfine, consistant à faire réagir cette alpha oléfine avec du monoxyde de carbone ou du monoxyde de carbone et de l'hydrogène et/ou un agent réducteur en présence d'un complexe catalytique constitué d'un précurseur de rhodium et d'un mélange contenant un ligand et au moins 1 % en poids de triphénylphosphine et au moins 5 % en poids de diphénylcyclohexylphosphine, de tris-(o-tolyl)phosphine, de tris-(p-tolyl)phosphine ou de (2-méthyl-phényl)diphénylphosphine.