METHODS FOR PRODUCING GALLIUM AND OTHER OXO/HYDROXO-BRIDGEGED METAL AQUO CLUSTERS

Metallic clusters can be produced by contacting a metal salt such as a metal nitrate with an organic reducing agent. Metals can be selected from a group consisting of metals exhibiting octahedral coordination, and nitrates of the selected metal or metals are contacted with, for example nitrosobenzen...

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Bibliographische Detailangaben
Hauptverfasser:	GATLIN, JASON, T, JOHNSON, DARREN, W, RATHER, ELISABETH
Format:	Patent
Sprache:	eng ; fre
Schlagworte:	ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM CHEMISTRY COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM,CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THERARE-EARTH METALS INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OFSOLID INORGANIC COMPOUNDS INORGANIC CHEMISTRY METALLURGY ORGANIC CHEMISTRY
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Beschreibung
Zusammenfassung:	Metallic clusters can be produced by contacting a metal salt such as a metal nitrate with an organic reducing agent. Metals can be selected from a group consisting of metals exhibiting octahedral coordination, and nitrates of the selected metal or metals are contacted with, for example nitrosobenzene. Binary, tertiary, or other clusters can be produced. L'invention concerne des grappes métalliques que l'on peut produire en mettant en contact un sel métallique, par exemple un nitrate métallique avec un agent réducteur organique. On peut choisir des métaux dans un groupe de métaux présentant une coordination octaèdre, et mettre les nitrates du métal ou des métaux choisi(s) en contact avec, par exemple, le nitrosobenzène. On peut notamment produire des grappes binaires et tertiaires.