EXPANDABLE POLYSTYRENE COMPOSITION

The invention relates to an expandable polystyrene composition in the form of expandable beads, comprising by weight (1) 100 parts of a styrene polymer, (2) from 2.2 to less than 4.0 parts of at least one blowing agent, and (3) from 0.01 to 0.4 part of at least one plasticising. The composition is p...

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Hauptverfasser: GALLICE, ALEXANDRE, WAECKERLE, UEW, CARLIER, CHRISTOPHE, BRES, PHILIPPE-LUC
Format: Patent
Sprache:eng ; fre
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Zusammenfassung:The invention relates to an expandable polystyrene composition in the form of expandable beads, comprising by weight (1) 100 parts of a styrene polymer, (2) from 2.2 to less than 4.0 parts of at least one blowing agent, and (3) from 0.01 to 0.4 part of at least one plasticising. The composition is particularly useful for manufacturing medium­ density expanded moulded polystyrene objects, particularly with a density from 40 to 190 g/l. The invention also relates to a process for manufacturing such objects, employing an expandable polystyrene composition in the form of beads containing by weight (1) 100 parts of a styrene polymer, (2) from 2.2 to less than 4.0 parts of at least one blowing agent, and (3) from 0 to 0.4 part of at least one plasticising agent. The process comprises (i) a pre-expansion stage by heating the expandable beads so as to form pre-expanded beads with a bulk density of 40 to 190 g/l, (ii) a stabilisation stage by contacting the pre-expanded beads with a gaseous medium at 0 to 40°C, under an absolute pressure of 50 to 160 kPa, for a period of 6 to 48 hours, and (iii) a moulding stage by introducing and heating the beads thus stabilised into a mould. The invention also relates to pre-expanded beads with a bulk density of 40 to 190 g/l, containing by weight (a) 100 parts of a styrene polymer, (b) from 0.5 to less than 3.0 parts of at least one blowing agent, and (c) from 0 to 0.4 part of at least one plasticising agent. L'invention concerne une composition de polystyrène expansible se présentant sous la forme de billes expansibles, comprenant, en poids (1) 100 parties d'un polymère styrène, (2) 2,2 à moins de 4,0 parties d'au moins un agent gonflant, et (3) 0,01 à 0,4 partie d'au moins un plastifiant. La composition est particulièrement utile pour la fabrication d'objets en polystyrène expansé moulé à densité moyenne, présentant notamment une densité de 40 à 190 g/l. L'invention porte également sur un procédé de fabrication desdits objets, au moyen d'une composition de polystyrène expansible se présentant sous la forme de billes contenant, en poids, (1) 100 parties d'un polymère styrène, (2) 2,2 à moins de 4,0 parties d'au moins un agent gonflant, et (3) 0 à 0,4 partie d'au moins un agent plastifiant. Le procédé de l'invention comprend (i) une étape de pré-expansion qui consiste à chauffer les billes expansibles de manière que des billes pré-expansées possédant une densité apparente de 40 à 90 g/l soient formées, (ii) une étape de stabili