Method and system for optimizing radio resources between UE and ENB during VoLTE call

A method and system is provided for optimizing Radio resources during a VoLTE call when ROHC is enabled by indicating an IP-ID value using an identifier in an Initial and Refresh (IR) packet. During the VoLTE call, when value of a static IP-ID is zero, the ROHC compressor appends an identifier in the IR packet and enables the identifier for indicating the static IP-ID value to the ROHC decompressor. Further, the ROHC compressor sends the IR packet to the ROHC decompressor by enabling the identifier for indicating the static IP-ID value during the ROHC context. The ROHC decompressor receives the IR packet and determines the identifier in the IR packet. If the identifier is enabled in the IR packet then the ROHC decompressor sets the IP-ID value as zero during generation of decompressed IP header.