Method of producing porous metal-carbon materials
A method for creating a metal-carbon composite. In one embodiment, the method includes the steps of providing a polymer Schiff base transition metal film precursor having a chemical structure of the formula [M(Schiff)]n and a recurring unit and a transition metal selected from the group consisting o...
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Zusammenfassung: | A method for creating a metal-carbon composite. In one embodiment, the method includes the steps of providing a polymer Schiff base transition metal film precursor having a chemical structure of the formula [M(Schiff)]n and a recurring unit and a transition metal selected from the group consisting of nickel, palladium, platinum, cobalt, copper, iron; Schiff is a tetradentate Schiff base ligand selected from the group consisting of Salen (residue of bis(salicylaldehyde)-ethylenediamine), Saltmen (residue of bis(salicylaldehyde)-tetramethylethylenediamine, Salphen (residue of bis-(salicylaldehyde)-o-phenylenediamine), a substituent in a Schiff base is selected from the group consisting of H-, and carbon-containing substituents, preferably CH3-, C2H5-, CH3O-, C2H5O-, and Y is a bridge in a Schiff base depositing the polymer Schiff base transition metal precursor film onto a support substrate; and heating the polymer Schiff base transition metal precursor film and support substrate in a furnace in an inert atmosphere. |
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