Perfluoroalkyl sulfonamides surfactants for photoresist rinse solutions

A method of modifying a surface of a photoresist material including exposing the photoresist material to an aqueous ionic surfactant solution and varying the pH of the aqueous ionic surfactant solution until a fluorochemical layer is formed in or on the photoresist material. The aqueous ionic surfac...

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Bibliographische Detailangaben
Hauptverfasser: Savu Patricia M, Pinnow Matthew J, Kehren Jason M
Format: Patent
Sprache:eng
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Zusammenfassung:A method of modifying a surface of a photoresist material including exposing the photoresist material to an aqueous ionic surfactant solution and varying the pH of the aqueous ionic surfactant solution until a fluorochemical layer is formed in or on the photoresist material. The aqueous ionic surfactant solution includes a perfluoroalkyl sulfonamide the formula: RfS02NH-R′ where Rf=CnF2n+1- and n=1 to 6, R′=-H, -CH3, and -CH2CH2OH. The aqueous ionic surfactant solution has a pH of within about 3 pH units of a pKa of the perfluoroalkyl sulfonamide.