Olefin-metathesis catalysts and method for preparing low-molecular-weight nitrile butadiene rubber

An olefin-metathesis catalyst is provided. The olefin-metathesis catalyst includes a magnetic carrier, a polymer having formula (I) grafted on the magnetic carrier, and a ruthenium complex loaded on the polymer. A method for preparing low-molecular-weight nitrile butadiene rubber is also provided. I...

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Hauptverfasser: HSIEH FENG-MING, WANG MEI-HUA, SHIH KUON, SU TING-YAO, CHEN CHUN-YEN
Format: Patent
Sprache:eng
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Zusammenfassung:An olefin-metathesis catalyst is provided. The olefin-metathesis catalyst includes a magnetic carrier, a polymer having formula (I) grafted on the magnetic carrier, and a ruthenium complex loaded on the polymer. A method for preparing low-molecular-weight nitrile butadiene rubber is also provided. In formula (I), one of X, Y and Z is nitrogen atom, the others are carbon atoms, R1 and R2, independently, include hydrogen, ester group, C1-10 alkyl group, C3-8 cycloalkyl group, 4-ring to 8-ring heterocycloalkyl or C6-10 aryl group, R3 includes hydrogen or C1-10 alkyl group, m ranges from 10 to 2,000, and n ranges from 0 to 1,000.