Polymerizable compositions containing (meth)acrylate monomers having sulfide linkages

Provided is a polymerizable composition including (meth)acrylate monomers having at least two sulfide (-S-) linkages in the monomer. The polymerizable compositions include a first (meth)acrylate monomer represented by the following Formula (I), where L1 is selected from a multivalent optionally subs...

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Hauptverfasser: GRAHAM MARVIN J, ZHOU HONGYING, BOJKOVA NINA V, MCCOLLUM GREGORY J, HEROLD ROBERT D, RETSCH, JR. WILLIAM H, HICKENBOTH CHARLES R
Format: Patent
Sprache:eng
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Zusammenfassung:Provided is a polymerizable composition including (meth)acrylate monomers having at least two sulfide (-S-) linkages in the monomer. The polymerizable compositions include a first (meth)acrylate monomer represented by the following Formula (I), where L1 is selected from a multivalent optionally substituted hydrocarbyl group optionally interrupted with at least one of -C(O)-, -S-, -O- and combinations thereof, and a divalent linking group represented by the following Formula (A). In Formula (A), Y is O or S. Also in Formula (I), L2 is independently for each n a divalent optionally substituted hydrocarbyl group optionally interrupted with at least one of -O- and -S-, R1 is independently selected for each n from hydrogen and methyl, and n is from 2 to 6. The polymerizable compositions also may include a polymerization moderator. Also provided are polymerizates including photochromic articles and optical elements prepared from such polymerizable compositions.