Bulk sulfidic mixed metal catalyst and methods for its manufacture and use in converting syngas to alcohol

A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10...

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Hauptverfasser: JANBROERS STEPHAN, PLANTENGA FRANS LODEWIJK, EIJSBOUTS-SPICKOVA SONA, STEENWINKEL EDGAR EVERT, HOMAN FREE HARMANNUS WILLEM, NUBERG EDWIN, OOGJEN BOB GERARDUS
Format: Patent
Sprache:eng
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Zusammenfassung:A process for sulfiding a cobalt-molybdenum bulk catalyst precursor to form a bulk sulfided alcohol synthesis catalyst. The process steps include contacting an oxidic bulk cobalt-molybdenum catalyst precursor with an amount of a sulfur-containing compound which is in the range of about 1 to about 10 moles of sulfur per mole of metals, at one or more temperatures at or in excess of about 300° C. in a medium which is substantially devoid of added hydrogen, so as to form a sulfided bulk cobalt-molybdenum catalyst product. Also described are processes for forming the catalyst precursor, processes for producing an alcohol using the catalyst product and the catalyst product itself.