Methods and reactor designs for producing phosphorus pentafluoride

Processes and systems for the production of phosphorus pentafluoride (PF5) through continuous fluorination of phosphorus are provided herein. A phosphorus feed stream and a fluorine feed stream are provided to a reactor, wherein they are reacted in a gas-gas or liquid-gas reaction to produce phospho...

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Hauptverfasser: POKROVSKI KONSTANTIN A, COTTRELL STEPHEN A, NAIR HARIDASAN K, UHRICH KEVIN, DEPRATO PHILIP, BRENNER DANIEL J, LULY MATTHEW H, MERKEL DANIEL C, SMITH ROBERT A
Format: Patent
Sprache:eng
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Zusammenfassung:Processes and systems for the production of phosphorus pentafluoride (PF5) through continuous fluorination of phosphorus are provided herein. A phosphorus feed stream and a fluorine feed stream are provided to a reactor, wherein they are reacted in a gas-gas or liquid-gas reaction to produce phosphorus pentafluoride (PF5). The phosphorus feed can be derived from white phosphorus or yellow phosphorus, and can be provided to the reactor as a liquid or a vapor. The fluorine can be provided to the reactor as a vapor, and preferably comprises elemental fluorine gas.