Cyclic catalytic upgrading of chemical species using metal oxide materials

Processes are disclosure which comprise alternately contacting an oxygen-carrying catalyst with a reducing substance, or a lower partial pressure of an oxidizing gas, and then with the oxidizing gas or a higher partial pressure of the oxidizing gas, whereby the catalyst is alternately reduced and th...

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Bibliographische Detailangaben
Hauptverfasser: WHITE JAMES H, ROLFE SARA L, SCHUTTE ERICK J
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:Processes are disclosure which comprise alternately contacting an oxygen-carrying catalyst with a reducing substance, or a lower partial pressure of an oxidizing gas, and then with the oxidizing gas or a higher partial pressure of the oxidizing gas, whereby the catalyst is alternately reduced and then regenerated to an oxygenated state. In certain embodiments, the oxygen-carrying catalyst comprises at least one metal oxide-containing material containing a composition having one of the following formulas: (a) CexByB′zB″Oδ, wherein B=Ba, Sr, Ca, or Zr; B′=Mn, Co, or Fe; B″=Cu; 0.01