Nanoscale rutile or anatase oxide and method for producing same

The invention relates to nanoscale rutile or oxide powder that is obtained by producing amorphous TiO2 by mixing an alcoholic solution with a titanium alcoholate and with an aluminum alcohalate and adding water and acid. The amorphous, aluminum-containing TiO2 is isolated by removing the solvent, an...

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1. Verfasser:	NONNINGER RALPH
Format:	Patent
Sprache:	eng
Schlagworte:	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM,CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THERARE-EARTH METALS COMPOUNDS THEREOF INORGANIC CHEMISTRY MANUFACTURE OR TREATMENT THEREOF METALLURGY NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS,MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES ASDISCRETE UNITS NANOTECHNOLOGY NON-METALLIC ELEMENTS PERFORMING OPERATIONS PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL THEIR RELEVANT APPARATUS TRANSPORTING
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Beschreibung
Zusammenfassung:	The invention relates to nanoscale rutile or oxide powder that is obtained by producing amorphous TiO2 by mixing an alcoholic solution with a titanium alcoholate and with an aluminum alcohalate and adding water and acid. The amorphous, aluminum-containing TiO2 is isolated by removing the solvent, and is redispersed in water in the presence of a tin salt. Thermal or hydrothermal post-processing yields rutile or oxide that can be redispersed to primary particle size. The n-rutile or the obtained oxide having a primary particle size ranging between 5 and 20 nm can be incorporated into all organic matrices so that they remain transparent. Photocatalytic activity is suppressed by lattice doping with trivalent ions. If the amorphous precursor is redispersed in alcohol, or not isolated, but immediately crystallized, an anatase is obtained that can be redispersed to primary particle size. A variation of the alcoholates allows production of the following components: ZrO2, ZnO, SnO2, ATO, In2O3, ITO, Y2O3, BaO, CaO, MgO, CeO2, and BaTiO.