Polyvinyl alcohol based polymer and method of manufacturing the same

The present invention provides polyvinyl alcohol based (PVA) whose solubility in water varies with a small temperature change to a sufficiently great degree. In manufacturing a polyvinyl alcohol based polymer by: progressing a transesterification reaction of a polyvinyl ester based polymer with alco...

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Bibliographische Detailangaben
Hauptverfasser: FUJIWARA NAOKI, KUSUDOU TAKESHI, YANAI HISAMICHI, TOKUDA YOSHIHIRO, TOKUYASU JIN, MIYATA KIMIKO
Format: Patent
Sprache:eng
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Zusammenfassung:The present invention provides polyvinyl alcohol based (PVA) whose solubility in water varies with a small temperature change to a sufficiently great degree. In manufacturing a polyvinyl alcohol based polymer by: progressing a transesterification reaction of a polyvinyl ester based polymer with alcohol in a liquid reaction mixture including the polyvinyl ester based polymer, the alcohol, and a basic compound; precipitating the polyvinyl ester based polymer, at least a part of which has been transesterified with the alcohol, out of the liquid reaction mixture; and further progressing the transesterification reaction in the liquid reaction mixture including the polyvinyl ester based polymer that has precipitated, the liquid reaction mixture has a temperature of 75° C. to 150° C. when the polyvinyl ester based polymer, at least a part of which has been transesterified, starts precipitating.