Manufacturable CoWP metal cap process for copper interconnects

A method to electrolessly plate a CoWP alloy on copper in a reproducible manner that is effective for a manufacturable process. In the method, a seed layer of palladium (Pd) is deposited on the copper by an aqueous seeding solution of palladium acetate, acetic acid and chloride. Thereafter, a comple...

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Bibliographische Detailangaben
Hauptverfasser: SMITH SEAN P. E, RUBINO JUDITH M, KRISHNAN MAHADEVAIYER, CANAPERI DONALD F, FLUEGEL JAMES E, HENRY RICHARD O, RESTAINO DARRYL D
Format: Patent
Sprache:eng
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Zusammenfassung:A method to electrolessly plate a CoWP alloy on copper in a reproducible manner that is effective for a manufacturable process. In the method, a seed layer of palladium (Pd) is deposited on the copper by an aqueous seeding solution of palladium acetate, acetic acid and chloride. Thereafter, a complexing solution is applied to remove any Pd ions which are adsorbed on surfaces other than the copper. Finally, a plating solution of cobalt (Co), tungsten (W) and phosphorous (P) is applied to the copper so as to deposit a layer of CoWP on the Pd seed and copper.