Polysiloxane sols method for the production and use thereof
Polysiloxane sols preparable by subjecting (1) in a first stage (A) a silicon compound of the general formula I: (ZoL-)mSi(H)n(R)p, (I) which is free of carbamate groups and where o is an integer from 1 to 5; m is 0, 1, 2 or 3; n is an integer from 1 to 4; p is 0, 1 , 2 or 3; Z is a reactive functio...
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| creator | THIEL LUCIEN HENKELMANN JOCHEN HOMMMES PETER NIEMEIER MANUELA RINK HEINZ-PETER |
| description | Polysiloxane sols preparable by subjecting (1) in a first stage (A) a silicon compound of the general formula I: (ZoL-)mSi(H)n(R)p, (I) which is free of carbamate groups and where o is an integer from 1 to 5; m is 0, 1, 2 or 3; n is an integer from 1 to 4; p is 0, 1 , 2 or 3; Z is a reactive functional group, excluding carbamate group; L is an at least divalent, linking, organic group; H is a hydrolyzable, monovalent, organic group or hydrolyzable atom; R is a nonhydrolyzable, monovalent, organic group; to partial hydrolysis and condensation in the presence (B) of at least one crosslinking agent, and then subjecting (2) in a further stage, the reaction mixture (1) to complete hydrolysis and condensation with (C) a hydrolyzable, carbamate-functional silicon compound of the general formula II: {[HR1N-(O)C-O-]rL-}sSi(H)t(R)u (II) where R1 is a hydrogen atom or group R; r is an integer from 1 to 5; s is 1, 2 or 3; t is 1, 2 or 3; u 0, 1 or 2; and their use as coating materials, adhesives, and sealing compounds and also for producing optical moldings and self-supporting films. |
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m is 0, 1, 2 or 3; n is an integer from 1 to 4; p is 0, 1 , 2 or 3; Z is a reactive functional group, excluding carbamate group; L is an at least divalent, linking, organic group; H is a hydrolyzable, monovalent, organic group or hydrolyzable atom; R is a nonhydrolyzable, monovalent, organic group; to partial hydrolysis and condensation in the presence (B) of at least one crosslinking agent, and then subjecting (2) in a further stage, the reaction mixture (1) to complete hydrolysis and condensation with (C) a hydrolyzable, carbamate-functional silicon compound of the general formula II: {[HR1N-(O)C-O-]rL-}sSi(H)t(R)u (II) where R1 is a hydrogen atom or group R; r is an integer from 1 to 5; s is 1, 2 or 3; t is 1, 2 or 3; u 0, 1 or 2; and their use as coating materials, adhesives, and sealing compounds and also for producing optical moldings and self-supporting films.</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | ADHESIVES APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS COMPOSITIONS BASED THEREON CORRECTING FLUIDS DYES FILLING PASTES INKS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS ORGANIC MACROMOLECULAR COMPOUNDS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING PERFORMING OPERATIONS POLISHES PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL SPRAYING OR ATOMISING IN GENERAL THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING USE OF MATERIALS THEREFOR WOODSTAINS |
| title | Polysiloxane sols method for the production and use thereof |
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