Polysiloxane sols method for the production and use thereof
Polysiloxane sols preparable by subjecting (1) in a first stage (A) a silicon compound of the general formula I: (ZoL-)mSi(H)n(R)p, (I) which is free of carbamate groups and where o is an integer from 1 to 5; m is 0, 1, 2 or 3; n is an integer from 1 to 4; p is 0, 1 , 2 or 3; Z is a reactive functio...
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Zusammenfassung: | Polysiloxane sols preparable by subjecting (1) in a first stage (A) a silicon compound of the general formula I: (ZoL-)mSi(H)n(R)p, (I) which is free of carbamate groups and where o is an integer from 1 to 5; m is 0, 1, 2 or 3; n is an integer from 1 to 4; p is 0, 1 , 2 or 3; Z is a reactive functional group, excluding carbamate group; L is an at least divalent, linking, organic group; H is a hydrolyzable, monovalent, organic group or hydrolyzable atom; R is a nonhydrolyzable, monovalent, organic group; to partial hydrolysis and condensation in the presence (B) of at least one crosslinking agent, and then subjecting (2) in a further stage, the reaction mixture (1) to complete hydrolysis and condensation with (C) a hydrolyzable, carbamate-functional silicon compound of the general formula II: {[HR1N-(O)C-O-]rL-}sSi(H)t(R)u (II) where R1 is a hydrogen atom or group R; r is an integer from 1 to 5; s is 1, 2 or 3; t is 1, 2 or 3; u 0, 1 or 2; and their use as coating materials, adhesives, and sealing compounds and also for producing optical moldings and self-supporting films. |
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