Method for the preparation of trimethylcyclohexyl-alkan-3-ols containing a high proportion of trans isomers

A method is described for the preparation of a trimethylcyclohexyl-alkan-3-ol containing a proportion of trans isomer of Formula D where R=H, Me, Et, n-propyl, iso-propyl, n-butyl, iso-butyl or tert-butyl and R1=Me, Et, n-propyl, iso-propyl, n-butyl, iso-butyl or tert-butyl, or of a mixture of sever...

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Bibliographische Detailangaben
Hauptverfasser:	SCH{HACEK OVER (AFER KLAUS, STRUWE HARTMUT, PICKENHAGEN WILHELM, SCHATKOWSKI DIETMAR, PANTEN JOHANNES
Format:	Patent
Sprache:	eng
Schlagworte:	ACYCLIC OR CARBOCYCLIC COMPOUNDS ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES APPARATUS THEREFOR CANDLES CHEMISTRY DETERGENTS ESSENTIAL OILS FATTY ACIDS THEREFROM GENERAL METHODS OF ORGANIC CHEMISTRY METALLURGY ORGANIC CHEMISTRY PERFUMES PRODUCING (PRESSING, EXTRACTION), REFINING AND PRESERVINGFATS, FATTY SUBSTANCES (e.g. LANOLIN), FATTY OILS AND WAXES,INCLUDING EXTRACTION FROM WASTE MATERIALS
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Beschreibung
Zusammenfassung:	A method is described for the preparation of a trimethylcyclohexyl-alkan-3-ol containing a proportion of trans isomer of Formula D where R=H, Me, Et, n-propyl, iso-propyl, n-butyl, iso-butyl or tert-butyl and R1=Me, Et, n-propyl, iso-propyl, n-butyl, iso-butyl or tert-butyl, or of a mixture of several such trimethylcyclohexyl-alkan-3-ols, wherein the method comprises catalytically hydrogenating corresponding compound(s) of Formula B in which R and R1 in each case have the indicated meanings, in the presence of a nickel catalyst, preferably of Raney nickel, and in an absence of catalytically active amounts of copper chromite.