Hybrid sol-gel barrier coatings

Hybrid sol-gel barrier coatings are produced by hydrolyzing a tetrafunctional alkoxide silicate and a silane having one or two pendant crosslinkable groups in water or water plus a water miscible organic solvent and a catalytic amount a protic acid, Lewis acid, or metal chelate, until a viscosity of...

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Bibliographische Detailangaben
Hauptverfasser:	LUCAS, PAUL C, VOLPE, RAYMOND A
Format:	Patent
Sprache:	eng
Schlagworte:	ADHESIVES CHEMICAL PAINT OR INK REMOVERS CHEMISTRY COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS CORRECTING FLUIDS DYES FILLING PASTES INKS LAYERED PRODUCTS LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT ORNON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM METALLURGY MISCELLANEOUS APPLICATIONS OF MATERIALS MISCELLANEOUS COMPOSITIONS NATURAL RESINS PAINTS PASTES OR SOLIDS FOR COLOURING OR PRINTING PERFORMING OPERATIONS POLISHES TRANSPORTING USE OF MATERIALS THEREFOR WOODSTAINS
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Beschreibung
Zusammenfassung:	Hybrid sol-gel barrier coatings are produced by hydrolyzing a tetrafunctional alkoxide silicate and a silane having one or two pendant crosslinkable groups in water or water plus a water miscible organic solvent and a catalytic amount a protic acid, Lewis acid, or metal chelate, until a viscosity of from about 2,600 to about 3,200 cps is obtained. The product is then diluted water or water plus a water miscible organic solvent, optionally containing a protic acid, Lewis acid, or metal chelate, until a viscosity of about 0.5 to about 10 cps is obtained. The diluted product is blended with a photoinitiator, coated onto a substrate, dried and irradiated to obtain oxygen barrier films having a very low oxygen transmission rate.