Process for the preparation of rare-earth sulphides from halides

The present invention concerns a process for the preparation of a rare-earth sulphide characterized in that a rare-earth halide is brought into the presence of an alkaline or aluminum halide and heated in the presence of hydrogen sulphide at a temperature which is sufficient to volatilize the halide...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: MACAUDIERE, PIERRE, PESCHER, YVETTE
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:The present invention concerns a process for the preparation of a rare-earth sulphide characterized in that a rare-earth halide is brought into the presence of an alkaline or aluminum halide and heated in the presence of hydrogen sulphide at a temperature which is sufficient to volatilize the halides. More particularly, the halide is a chloride, the rare-earth is cerium and the alkali is sodium.