Reactive melt extrusion grafting of thermoplastic polyvinyl alcohol/polyolefin blends

A method for preparing a compatible blend of polyolefin and thermoplastic polyvinyl alcohol comprising: (a) melting polyolefin in the initial elements of a melt extruder, (b) adding and melt blending an unsaturated carboxylic acid or anhydride with the melted polyolefin downstream in the extruder, (...

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Bibliographische Detailangaben
Hauptverfasser:	FAMILI, AMIR, NANGERONI, JAMES F, ROBESON, LLOYD M
Format:	Patent
Sprache:	eng
Schlagworte:	AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING CHEMISTRY COMPOSITIONS BASED THEREON COMPOSITIONS OF MACROMOLECULAR COMPOUNDS INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS PERFORMING OPERATIONS SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR SHAPING OR JOINING OF PLASTICS THEIR PREPARATION OR CHEMICAL WORKING-UP TRANSPORTING WORKING OF PLASTICS WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL
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Beschreibung
Zusammenfassung:	A method for preparing a compatible blend of polyolefin and thermoplastic polyvinyl alcohol comprising: (a) melting polyolefin in the initial elements of a melt extruder, (b) adding and melt blending an unsaturated carboxylic acid or anhydride with the melted polyolefin downstream in the extruder, (c) adding peroxide to the melt blend and grafting the unsaturated carboxylic acid or anhydride onto the polyolefin, and (d) melt blending thermoplastic PVOH into the grafted polyolefin/unsaturated carboxylic acid or anhydride melt mixture.